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Issue 8, 1984
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Chemical shift parametrization for metal-ion nuclear magnetic resonance spectroscopy of d6 transition metal complexes

Nenad Juranić 

Abstract

Metal-ion chemical shifts in cobalt(III), ruthenium(II), rhodium(III), and platinum(IV) complexes have been parametrized into metal and ligand contributions. The resulting metal-ion chemical shifts are calculated with a fair accuracy that allows analytical applications. Apparently diverse trends in the metal-ion chemical shifts for complexes of class A and B metal ions have been accommodated in a single scheme. An analysis of the ligand parameters shows that ligands including first-period ligating atoms can be ordered according to the increasing shielding of the metal ion into a magnetochemical series.

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Article type: Paper
DOI: 10.1039/DT9840001537
Citation: J. Chem. Soc., Dalton Trans., 1984,0, 1537-1540
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    Chemical shift parametrization for metal-ion nuclear magnetic resonance spectroscopy of d6 transition metal complexes

    N. Juranić, J. Chem. Soc., Dalton Trans., 1984, 0, 1537
    DOI: 10.1039/DT9840001537

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