Reaction of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane with P(CN)3 and As(CN)3 yields stable insertion products, in which the nitriles are rearranged to the corresponding isonitrile structures.
H. W. Roesky and K. S. Dhathathreyan, J. Chem. Soc., Chem. Commun., 1984, 1053 DOI: 10.1039/C39840001053
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