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Issue 6, 1984
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[Cu6S17]2–, a novel binary discrete polynuclear CuI complex with several interesting structural features: the arrangement of the metal atoms and co-ordination of ligands

Achim Müller,  Michael Römer,  Hartmut Bögge,  Erich Krickemeyer  and  Dieter Bergmann 

Abstract

The structure of [PPh4]2[Cu6S17], obtained from Cu(acac)2(Hacac = acetylacetone) and PPh4Br in an ethanol solution of polysulphide, contains an unusual arrangement of metal atoms (which can only approximately be described as two distorted Cu tetrahedral sharing one edge) and novel ligand co-ordination of polysulphide (S42– and S52–) ions.

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Article type: Paper
DOI: 10.1039/C39840000348
Citation: J. Chem. Soc., Chem. Commun., 1984,0, 348-349
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    [Cu6S17]2–, a novel binary discrete polynuclear CuI complex with several interesting structural features: the arrangement of the metal atoms and co-ordination of ligands

    A. Müller, M. Römer, H. Bögge, E. Krickemeyer and D. Bergmann, J. Chem. Soc., Chem. Commun., 1984, 0, 348
    DOI: 10.1039/C39840000348

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