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Issue 0, 1983
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Organoiron complexes in organic synthesis. Part 27. Synthesis and reactivity of tricarbonyliron derivatives of 1,2-disubstituted 4-alkoxycyclohexadienylium cations

Anthony J. Pearson,  Trevor R. Perrior  and  David A. Griffin 

Abstract

The synthesis, and reactions with stable enolate nucleophiles, of 1,2-disubstituted 4-alkoxycyclohex-adienylium(tricarbonyl)iron complexes (3a), (3b), (3c), and (3d) is described. Only the 1,2-dimethyl-4-isopropoxycyclohexadienylium complex (3b) was found to react with nucleophiles with sufficiently high regioselectivity to allow a useful method of preparation of 3,4,4-trisubstituted cyclohexenones.

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Article type: Paper
DOI: 10.1039/P19830000625
Citation: J. Chem. Soc., Perkin Trans. 1, 1983,0, 625-631
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    Organoiron complexes in organic synthesis. Part 27. Synthesis and reactivity of tricarbonyliron derivatives of 1,2-disubstituted 4-alkoxycyclohexadienylium cations

    A. J. Pearson, T. R. Perrior and D. A. Griffin, J. Chem. Soc., Perkin Trans. 1, 1983, 0, 625
    DOI: 10.1039/P19830000625

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