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Issue 10, 1983
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X-ray photoelectron spectroscopy, X-ray auger electron spectroscopy and electron spin resonance studies of the reduction of some solid metal 12-molybdophosphates

Masamichi Akimoto,  Kenji Shima  and  Etsuro Echigoya 

Abstract

The X.p.s. (X-ray photoelectron spectroscopy), X.A.e.s. (X-ray Auger electron spectroscopy), and e.s.r. (electron spin resonance) studies of palladium, zinc, silver and copper(II) 12-molybdophosphates (3–) in the solid state have been made with reference to the behaviour of electrons formed by reduction with hydrogen. The results obtained indicate that the electrons are more preferentially captured by the cations than by Mo6+ atoms in 12-molybdophosphate anions when the cations are of high electron affinity. The significance of this finding in relation to the role played by cations in heterogeneous catalytic oxidations is discussed.

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Article type: Paper
DOI: 10.1039/F19837902467
Citation: J. Chem. Soc., Faraday Trans. 1, 1983,79, 2467-2474
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    X-ray photoelectron spectroscopy, X-ray auger electron spectroscopy and electron spin resonance studies of the reduction of some solid metal 12-molybdophosphates

    M. Akimoto, K. Shima and E. Echigoya, J. Chem. Soc., Faraday Trans. 1, 1983, 79, 2467
    DOI: 10.1039/F19837902467

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