Optical electronegativity, χ*, of transition-metal ions in simple compounds

John A. Duffy

doi:10.1039/DT9830001475

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Journal of the Chemical Society, Dalton Transactions

Issue 7, 1983

The international journal for inorganic, organometallic and bioinorganic chemistry

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Optical electronegativity, χ*, of transition-metal ions in simple compounds

John A. Duffy

J. Chem. Soc., Dalton Trans., 1983, 1475-1478

DOI: 10.1039/DT9830001475

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Abstract
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The difference between simple binary compounds and complexes is discussed in the context of charge-transfer (electron-transfer) absorption spectroscopy and correlations involving the optical electronegativities χ* and χ_opt. Using existing data, mainly for binary chlorides and bromides, values of χ* are obtained for Cr³⁺, Mn²⁺, Fe²⁺, Co²⁺, and Ni²⁺, and applied to binary sulphides and doped zinc sulphide crystals.

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Journal of the Chemical Society, Dalton Transactions

Optical electronegativity, χ*, of transition-metal ions in simple compounds

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