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Issue 7, 1983
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Optical electronegativity, χ*, of transition-metal ions in simple compounds

Abstract

The difference between simple binary compounds and complexes is discussed in the context of charge-transfer (electron-transfer) absorption spectroscopy and correlations involving the optical electronegativities χ* and χopt. Using existing data, mainly for binary chlorides and bromides, values of χ* are obtained for Cr3+, Mn2+, Fe2+, Co2+, and Ni2+, and applied to binary sulphides and doped zinc sulphide crystals.

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Article type: Paper
DOI: 10.1039/DT9830001475
Citation: J. Chem. Soc., Dalton Trans., 1983, 1475-1478
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    Optical electronegativity, χ*, of transition-metal ions in simple compounds

    J. A. Duffy, J. Chem. Soc., Dalton Trans., 1983, 1475
    DOI: 10.1039/DT9830001475

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