Nuclear quadrupole resonance and stereochemistry. Part 7. The axial and equatorial chlorine atoms in octahedral complexes of antimony pentachloride, SbCl5L (L = donor ligand)

Joyce Rupp-Bensadon; Edwin A. C. Lucken

doi:10.1039/DT9830000019

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Nuclear quadrupole resonance and stereochemistry. Part 7. The axial and equatorial chlorine atoms in octahedral complexes of antimony pentachloride, SbCl₅L (L = donor ligand)

Joyce Rupp-Bensadon and Edwin A. C. Lucken

Abstract

Chlorine-35 and ^121,123Sb n.q.r. frequencies and their temperature dependencies for various octahedral complexes of antimony pentachloride, SbCl₅L (L = donor ligand), are reported. Assignments of ³⁵Cl resonances to axial or equatorial chlorine atoms of the SbCl₅ fragment have been possible in some cases. There are no apparent systematic differences between the frequencies of the axial or equatorial chlorine atoms, such differences as there are being masked by crystal-field effects of similar magnitude.

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Article type: Paper

DOI: 10.1039/DT9830000019

Citation: J. Chem. Soc., Dalton Trans., 1983,0, 19-24

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Nuclear quadrupole resonance and stereochemistry. Part 7. The axial and equatorial chlorine atoms in octahedral complexes of antimony pentachloride, SbCl₅L (L = donor ligand)

J. Rupp-Bensadon and E. A. C. Lucken, J. Chem. Soc., Dalton Trans., 1983, 0, 19
DOI: 10.1039/DT9830000019
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Journal of the Chemical Society, Dalton Transactions

Nuclear quadrupole resonance and stereochemistry. Part 7. The axial and equatorial chlorine atoms in octahedral complexes of antimony pentachloride, SbCl₅L (L = donor ligand)

Abstract

Nuclear quadrupole resonance and stereochemistry. Part 7. The axial and equatorial chlorine atoms in octahedral complexes of antimony pentachloride, SbCl₅L (L = donor ligand)

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