Cyclo-octa-1,5-diene is di-oxygenated by RhCl(Ph3P)3O2 at room temperature in a regioselective reaction leading to cyclo-octane-1,4-dione; the reaction is catalytic under aerobic conditions.
L. Carlton, G. Read and M. Urgelles, J. Chem. Soc., Chem. Commun., 1983, 586 DOI: 10.1039/C39830000586
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