The reaction of some cyclic and open-chain disulphides with methyl trifluoromethanesulphonate

Michael Ravenscroft; Roger M. G. Roberts; John G. Tillett

doi:10.1039/P29820001569

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Journal of the Chemical Society, Perkin Transactions 2

Issue 12, 1982

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The reaction of some cyclic and open-chain disulphides with methyl trifluoromethanesulphonate

Michael Ravenscroft , Roger M. G. Roberts and John G. Tillett

J. Chem. Soc., Perkin Trans. 2, 1982, 1569-1572

DOI: 10.1039/P29820001569

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The rates of reaction of methyl trifluoromethanesulphonate with a number of cyclic and open-chain disulphides have been studied at various temperatures. The main products of the reactions have been identified as the corresponding methylsulphonium salts. The difference in reactivity between the fivemembered and other disulphides arises from a combination of both enthalpy and entropy effects.

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Journal of the Chemical Society, Perkin Transactions 2

The reaction of some cyclic and open-chain disulphides with methyl trifluoromethanesulphonate

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