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Salvinorin, isolated from Salvia divinorum, has been shown by spectroscopic and X-ray-crystallographic methods to be a trans-neoclerodane diterpene of structure (1). Crystals of compound (1) are orthorhombic, space group P212121 with a= 6.368(2), b= 11.338(3), c= 30.710(6)Å, and Z= 4. The structure was refined by leastsquares to R 0.052 and R′ 0.056.
A. Ortega, J. F. Blount and P. S. Manchand, J. Chem. Soc., Perkin Trans. 1, 1982, 2505 DOI: 10.1039/P19820002505
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