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Issue 0, 1982
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Synthetic enzymes. Part 2. Catalytic asymmetric epoxidation by means of polyamino-acids in a triphase system

Abstract

The asymmetric epoxidation of several chalcones and other electron-poor olefins, in the presence of catalytic amounts of poly-(S)-amino-acids in a triphase system with optical yields of up to 96% is described. The influence of the molecular structure of the catalysts and substrates, the solvent, and the temperature on the stereochemistry is discussed.

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Article type: Paper
DOI: 10.1039/P19820001317
Citation: J. Chem. Soc., Perkin Trans. 1, 1982, 1317-1324
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    Synthetic enzymes. Part 2. Catalytic asymmetric epoxidation by means of polyamino-acids in a triphase system

    S. Juliá, J. Guixer, J. Masana, J. Rocas, S. Colonna, R. Annuziata and H. Molinari, J. Chem. Soc., Perkin Trans. 1, 1982, 1317
    DOI: 10.1039/P19820001317

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