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Issue 11, 1982
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Cationic rhodium(I) complex-catalysed asymmetric isomerisation of allylamines to optically active enamines

Abstract

The cationic rhodium(I) complex(+)- or (–)-2,2′bis(diphenylphosphino)-1,1′-binaphthyl(cyclo-octa-1,5-diene)rhodium perchlorate, effectively catalyses the isomersiation of N,N-diethylnerylamine or N,N-diethylgeranylamine to produce optically active N,N-diethylcitronellal-(E)-enamine with excellent enantioselectivity (> ca. 95% enantiomeric excess) and chemoselectivity (> ca. 98%).

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Article type: Paper
DOI: 10.1039/C39820000600
Citation: J. Chem. Soc., Chem. Commun., 1982, 600-601
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    Cationic rhodium(I) complex-catalysed asymmetric isomerisation of allylamines to optically active enamines

    K. Tani, T. Yamagata, S. Otsuka, S. Akutagawa, H. Kumobayashi, T. Taketomi, H. Takaya, A. Miyashita and R. Noyori, J. Chem. Soc., Chem. Commun., 1982, 600
    DOI: 10.1039/C39820000600

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