SCHEDULED MAINTENANCE
The cationic rhodium(I) complex(+)- or (–)-2,2′bis(diphenylphosphino)-1,1′-binaphthyl(cyclo-octa-1,5-diene)rhodium perchlorate, effectively catalyses the isomersiation of N,N-diethylnerylamine or N,N-diethylgeranylamine to produce optically active N,N-diethylcitronellal-(E)-enamine with excellent enantioselectivity (> ca. 95% enantiomeric excess) and chemoselectivity (> ca. 98%).
K. Tani, T. Yamagata, S. Otsuka, S. Akutagawa, H. Kumobayashi, T. Taketomi, H. Takaya, A. Miyashita and R. Noyori, J. Chem. Soc., Chem. Commun., 1982, 600 DOI: 10.1039/C39820000600
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