Issue 9, 1982

Tungsten (IV) carbenes for the metathesis of olefins. Direct observation and identification of the chain carrying carbene complexes in a highly active catalyst system

Abstract

On addition of aluminium halides to the carbene complexes W(CHBut)(OCH2But)2X2 conversion into highly active catalysts for olefin metathesis occurs; the nature of the initiating and propagating species in olefin metathesis has been identified by n.m.r. spectroscopy.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 514-516

Tungsten (IV) carbenes for the metathesis of olefins. Direct observation and identification of the chain carrying carbene complexes in a highly active catalyst system

J. Kress, M. Wesolek and J. A. Osborn, J. Chem. Soc., Chem. Commun., 1982, 514 DOI: 10.1039/C39820000514

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