Issue 22, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

The RuII(OH2)–RuIV(O) couple in a ruthenium complex of 2-(phenylazo)pyridine : homogeneous catalysis of the oxidation of water to dioxygen

Sreebrata Goswami,   Akhil R. Chakravarty  and  Animesh Chakravorty  

Abstract

In acidic solution [RuII(OH2)(py)L2]2+ can be oxidised to [RuIV(O)(py) L2]2+ in a single reversible step (E°298= 1.20V) and the oxidised complex catalyses the dehydorgenation of water to dioxygen in the presence of Ce4+[py = pyridine; L = 2-(phenylazo)pyridine].

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Article information

DOI
https://doi.org/10.1039/C39820001288
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1288-1289

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The RuII(OH2)–RuIV(O) couple in a ruthenium complex of 2-(phenylazo)pyridine : homogeneous catalysis of the oxidation of water to dioxygen

S. Goswami, A. R. Chakravarty and A. Chakravorty, J. Chem. Soc., Chem. Commun., 1982, 1288 DOI: 10.1039/C39820001288

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