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Issue 14, 1982
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Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh3)2]

Abstract

The first metallabenzene,[O[graphic omitted]H)(CO)(PPh3)2] has been prepared from [Os(Co)(CS)(PPh3)3] and ethyen; X- ray crystal structure determination reveals a planar six-membered ring with no significant alternation of C–C bond lengths thus supporting the idea of electron delocalization within the ring.

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Article type: Paper
DOI: 10.1039/C39820000811
Citation: J. Chem. Soc., Chem. Commun., 1982,0, 811-813
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    Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh3)2]

    G. P. Elliott, W. R. Roper and J. M. Waters, J. Chem. Soc., Chem. Commun., 1982, 0, 811
    DOI: 10.1039/C39820000811

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