SCHEDULED MAINTENANCE
The syntheses of adrenaline-15-crown-5 and adrenaline-18-crown-6 starting from acetovanillone are reported, together with the properties of these compounds. Alkali and alkaline-earth metal complexes of these ligands have been prepared. A method of separating crown ethers based on their preferential complexation of barium is discussed.
D. E. Fenton, D. Parkin and R. F. Newton, J. Chem. Soc., Perkin Trans. 1, 1981, 449 DOI: 10.1039/P19810000449
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