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Issue 7, 1981
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Aluminium-27 nuclear magnetic resonance studies of heteropolyanions containing aluminium as heteroatom

Abstract

The preparation of [AlW12O40]5– and of [AlMo6O21]3– has been monitored by 27Al n.m.r. spectroscopy. It is possible to distinguish between aluminium in octahedral and tetrahedral environments. The preparation of [AlW12O40]5– gives rise to four species containing aluminium of which one is the desired product, one is probably a protonated form of it, and one may be the 2 : 18 (Al : W) anion.

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Article type: Paper
DOI: 10.1039/DT9810001615
Citation: J. Chem. Soc., Dalton Trans., 1981,0, 1615-1616
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    Aluminium-27 nuclear magnetic resonance studies of heteropolyanions containing aluminium as heteroatom

    J. W. Akitt and A. Farthing, J. Chem. Soc., Dalton Trans., 1981, 0, 1615
    DOI: 10.1039/DT9810001615

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