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Issue 18, 1981
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Remarkably easy one-electron reduction of 16-electron molybdenum nitrosyls: mechanistic implications for the formation of alkoxy, amido, hydrazido, and thiolato complexes containing the tris-3,5-dimethylpyrazolylborato-ligand

Jon A. McCleverty  and  Nabil El Murr 

Abstract

Reduction of [Mo{HB(3,5-Me2C3HN2)3}(NO)I2], A, is achieved electrochemically intetrahydrofuran (Pt or C electrodes), and in basic solvents chemically, giving paramagnetic A– from which I– dissociates affording paramagnetic [Mo{HB(Me2C3NH2)3}(NO)I]; these reduction products are important intermediates in the formation of [Mo{HB(Me2C3HN2)3}(NO)IQ], where Q = OR, NHR, NHNR1R2, and SR, from A and ROH, RNH2 R1R2NNH2, and RSH.

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Article type: Paper
DOI: 10.1039/C39810000960
Citation: J. Chem. Soc., Chem. Commun., 1981,0, 960-961
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    Remarkably easy one-electron reduction of 16-electron molybdenum nitrosyls: mechanistic implications for the formation of alkoxy, amido, hydrazido, and thiolato complexes containing the tris-3,5-dimethylpyrazolylborato-ligand

    J. A. McCleverty and N. E. Murr, J. Chem. Soc., Chem. Commun., 1981, 0, 960
    DOI: 10.1039/C39810000960

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