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Issue 8, 1981
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Preparation and crystal structures of the first alkali-rich sodium aluminates Na7Al3O8 and Na5AlO4

Abstract

X-Ray crystal structure determinations of two sodium aluminates have shown Na5AlO4(orthorhombic, space group pbca) to contain discrete AlO4 tetrahedra and Na7Al3O8(triclinic, P[1 with combining macron]) to contain a novel ring structure made up of six AlO4 tetrahedra which are linked by four oxygen bridges to form an infinite chain.

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Article type: Paper
DOI: 10.1039/C39810000379
Citation: J. Chem. Soc., Chem. Commun., 1981,0, 379-381
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    Preparation and crystal structures of the first alkali-rich sodium aluminates Na7Al3O8 and Na5AlO4

    M. G. Barker, P. G. Gadd and M. J. Begley, J. Chem. Soc., Chem. Commun., 1981, 0, 379
    DOI: 10.1039/C39810000379

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