Issue 9, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Some transition metal complexes of pentakis(methoxycarbonyl)cyclopentadiene: water-soluble metallocenes, and the X-ray crystal structure of Ru(η-C5H5)[η-C5(CO2Me)5]

Michael I. Bruce,   Brian W. Skelton,   Robert C. Wallis,   Jennifer K. Walton,   Allan H. White  and  Michael L. Williams  

Abstract

Some metal derivatives of the [C5(CO2Me)5]– anion (cpp–) are described, of which transition metal complexes M(cpp)2 are fully ionised in aqueous solution and the mixed complex Ru(η-C5H5)[η-C5(CO2Me)5] contains a symmetrically bonded cpp ring; covalent Group IB metal complexes M1(cpp)(PPh3) react further with PPh3 to give ionic [M(PPh3)2](cpp).

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Article information

DOI
https://doi.org/10.1039/C39810000428
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 428-430

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Some transition metal complexes of pentakis(methoxycarbonyl)cyclopentadiene: water-soluble metallocenes, and the X-ray crystal structure of Ru(η-C5H5)[η-C5(CO2Me)5]

M. I. Bruce, B. W. Skelton, R. C. Wallis, J. K. Walton, A. H. White and M. L. Williams, J. Chem. Soc., Chem. Commun., 1981, 428 DOI: 10.1039/C39810000428

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