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Issue 24, 1980
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Oxidative dimerisation of an anilido-complex of platinum; X-ray structure of [Pt2Cl2(PEt3)4N2C12H10]+[PF6]

Abstract

The reaction of (PhNH)Pt(PEt3)2Cl with AgPF6 gives a weakly paramagnetic benzidine (4,4′-diaminobiphenyl) complex, which undergoes reversible deprotonation; an X-ray crystal structure of the deprotonated complex shows that the benzidine ligand has a marked quinonoid character.

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Article type: Paper
DOI: 10.1039/C39800001216
Citation: J. Chem. Soc., Chem. Commun., 1980,0, 1216-1218
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    Oxidative dimerisation of an anilido-complex of platinum; X-ray structure of [Pt2Cl2(PEt3)4N2C12H10]+[PF6]

    N. W. Alcock, R. D. O'Sullivan and A. W. Parkins, J. Chem. Soc., Chem. Commun., 1980, 0, 1216
    DOI: 10.1039/C39800001216

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