High co-ordination numbers for methylmercury(II); X-ray and 1H n.m.r. studies of [MeHgL]NO3(L = 4,4′,4″-triethyl-2,2′:6′,2″-terpyridyl and di-2-pyridylmethane)

Allan J. Canty; Glen Hayhurst; Narongsak Chaichit; Bryan M. Gatehouse

doi:10.1039/C39800000316

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Journal of the Chemical Society, Chemical Communications

Issue 7, 1980

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High co-ordination numbers for methylmercury(II); X-ray and ¹H n.m.r. studies of [MeHgL]NO₃(L = 4,4′,4″-triethyl-2,2′:6′,2″-terpyridyl and di-2-pyridylmethane)

Allan J. Canty , Glen Hayhurst , Narongsak Chaichit and Bryan M. Gatehouse

J. Chem. Soc., Chem. Commun., 1980, 316-318

DOI: 10.1039/C39800000316

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Abstract
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Methylmercury(II) forms complexes [MeHgL]NO₃(L = 2,2′:6′,2″-terpyridyls and di-2-pyridylmethane) where the ligands L are bidentate in methanol, but tridentate and bidentate, respectively, in the solid state with co-ordination geometries for mercury based on a near linear dominant C–Hg–N unit with additional weak Hg–N bonding.

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Journal of the Chemical Society, Chemical Communications

High co-ordination numbers for methylmercury(II); X-ray and ¹H n.m.r. studies of [MeHgL]NO₃(L = 4,4′,4″-triethyl-2,2′:6′,2″-terpyridyl and di-2-pyridylmethane)

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