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Issue 3, 1980
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Photosensitized electron-transfer reactions of phenylacetylene

Abstract

Phenylacetylene (A) reacts with excited sensitizers (S) to produce radical ions (S)·, (A)·+, which react as geminate or separated pairs with (A) to give a dimeric radical cation (A+–·A); the latter reacts with nitriles to give pyridines (1) or with nitromethane leading to an oxidation product (2) and a dimer (1-phenylnaphthalene) is also formed via the geminate pair.

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Article type: Paper
DOI: 10.1039/C39800000126
Citation: J. Chem. Soc., Chem. Commun., 1980, 126-128
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    Photosensitized electron-transfer reactions of phenylacetylene

    S. L. Mattes and S. Farid, J. Chem. Soc., Chem. Commun., 1980, 126
    DOI: 10.1039/C39800000126

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