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Issue 23, 1980
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Synthesis and X-ray crystal structure of [(OC)3Fe(µ-Ph2PCHPPh2)FeH(CO)3], and the synthesis of the bridging vinylidene complex [Fe2(µ-C[double bond, length half m-dash]CH2)(µ-CO)(CO)2(η-C5H5)2]

Gordon M. Dawkins,  Michael Green,  John C. Jeffery  and  F. Gordon A. Stone 

Abstract

Reaction of the di-iron complex [Fe2(µ-CO)(dppm)(CO)6](dppm = Ph2PCH2PPh2) with methyllithium followed by CF3CO2H gives the compound [(OC)3[graphic omitted]eH(CO)3], the structure of which was established by X-ray crystallography; in contrast, with the same reagents [Fe2(CO)4(η-C5H5)2] affords the vinylidene complex [Fe2(µ-C[double bond, length half m-dash]CH2)(µ-CO)(CO)2(η-C5H5)2].

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Article type: Paper
DOI: 10.1039/C39800001120
Citation: J. Chem. Soc., Chem. Commun., 1980,0, 1120-1122
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    Synthesis and X-ray crystal structure of [(OC)3Fe(µ-Ph2PCHPPh2)FeH(CO)3], and the synthesis of the bridging vinylidene complex [Fe2(µ-C[double bond, length half m-dash]CH2)(µ-CO)(CO)2(η-C5H5)2]

    G. M. Dawkins, M. Green, J. C. Jeffery and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1980, 0, 1120
    DOI: 10.1039/C39800001120

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