Activation volumes for reactions of [Fe(4-Me-phen)3]2+ with cyanide and with peroxodisulphate, and of Mo(bipy)(CO)4 with cyanide in various solvents suggest that cyanide or peroxodisulphate desolvation is a dominant feature in transition state formation.
J. Burgess, A. J. Duffield and R. Sherry, J. Chem. Soc., Chem. Commun., 1980, 350 DOI: 10.1039/C39800000350
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