Issue 6, 1980

Synthesis and mechanism of formation of dicarbonyl(η4-trimethylenemethane)(η5-pentamethylcyclopentadienyl)molybdenum tetrafluoroborate

Abstract

Reaction of [Mo(CO)3(η5-C5Me5)]BF4 generated from [Mo(CO)3(η5-C5Me5)]2 and AgBF4 with methylenecyclopropane, cis-, and trans-2,3-dimethylmethylenecyclopropanes affords dicarbonyl(η4-trimethylenemethane)(η5-pentamethylcyclopentadienyl)molybdenum tetrafluoroborate complexes, the stereochemistry of the reactions implicating a disrotatory ring-opening reaction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 267-268

Synthesis and mechanism of formation of dicarbonyl(η4-trimethylenemethane)(η5-pentamethylcyclopentadienyl)molybdenum tetrafluoroborate

S. G. Barnes and M. Green, J. Chem. Soc., Chem. Commun., 1980, 267 DOI: 10.1039/C39800000267

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