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Issue 0, 1979
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Photolysis of ferrocenyl-olefins and -ethers in alcohols

Christopher Baker  and  William M. Horspool 

Abstract

The irradiation of solutions of 2-ferrocenylpropene and ferrocenylethylene in methanol and ethanol has been studied. The primary photochemical process is interpreted as involving ferrocenyl carbocation intermediates which yield ferrocenyl ethers. These ethers are themselves photolabile, yielding 2-ferrocenylpropane and 2,3-diferrocenyl-2,3-dimethylbutane from 2-ferrocenylpropene, and ferrocenylethane and 2,3-diferrocenylbutane from ferrocenylethylene. These latter reactions are thought to involve ferrocenyl free radicals.

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Article type: Paper
DOI: 10.1039/P19790001862
Citation: J. Chem. Soc., Perkin Trans. 1, 1979,0, 1862-1865
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    Photolysis of ferrocenyl-olefins and -ethers in alcohols

    C. Baker and W. M. Horspool, J. Chem. Soc., Perkin Trans. 1, 1979, 0, 1862
    DOI: 10.1039/P19790001862

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