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Issue 0, 1979
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Unsaturated carbohydrates. Part 21. A carbocyclic ring closure of a hex-5-enopyranoside derivative

Abstract

Heating of the unsaturated glycoside triester (1) in refluxing aqueous acetone with mercury(II) chloride gave the cyclohexenone derivative (4) in high yield in a reaction which represents a new means of obtaining functionalised carbocyclic compounds from carbohydrates. From compound (4), the substituted cyclohexenone (5) and thence the phenol (6) were prepared.

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Article type: Paper
DOI: 10.1039/P19790001455
Citation: J. Chem. Soc., Perkin Trans. 1, 1979, 1455-1458
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    Unsaturated carbohydrates. Part 21. A carbocyclic ring closure of a hex-5-enopyranoside derivative

    R. J. Ferrier, J. Chem. Soc., Perkin Trans. 1, 1979, 1455
    DOI: 10.1039/P19790001455

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