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Electro-organic reactions. Part 13. The anodic acetoxylation of methyl oleate

Chitra Adams,  Edwin N. Frankel  and  James H. P. Utley 

Abstract

Efficient anodic mono- and di-acetoxylation of methyl oleate is described. Acetoxylation is consecutive and conditions may be adjusted to give a maximum of either 60% monoacetoxylation or 85% diacetoxylation. Both mono- and di-substituted products are a complex mixture of isomers but the products of exhaustive electrolysis are mainly 9,10-diacetoxyoctadec-7- or -11-enoate. A mechanistic rationalisation is proposed.

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Article type: Paper
DOI: 10.1039/P19790000353
Citation: J. Chem. Soc., Perkin Trans. 1, 1979,0, 353-356
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    Electro-organic reactions. Part 13. The anodic acetoxylation of methyl oleate

    C. Adams, E. N. Frankel and J. H. P. Utley, J. Chem. Soc., Perkin Trans. 1, 1979, 0, 353
    DOI: 10.1039/P19790000353

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