Infrared and nuclear quadrupole resonance studies of the phase transitions of para-dichlorobenzene

Somnath Ganguly; J. R. Fernandes; D. Bahadur; C. N. R. Rao

doi:10.1039/F29797500923

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Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Issue 0, 1979

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics was published from 1972 - 1989. In 1990 it continued as Journal of the Chemical Society, Faraday Transactions.

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Infrared and nuclear quadrupole resonance studies of the phase transitions of para-dichlorobenzene

Somnath Ganguly, J. R. Fernandes, D. Bahadur and C. N. R. Rao

J. Chem. Soc., Faraday Trans. 2, 1979,75, 923-928

DOI: 10.1039/F29797500923

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The α→γ→α→β transitions of para-dichlorobenzene have been studied by employing infrared and n.q.r. spectroscopy as well as differential scanning calorimetry. The γ phase is associated with considerably higher values of some of the intramolecular vibration frequencies. The α→γ transition shows athermal nucleation behaviour as in martensitic transitions. Intermolecular vibration bands around 46 and 85 cm^–1 present in γ and α phases disappear in the β phase. The α→β transition seems to be associated with some orientational disorder.

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Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Infrared and nuclear quadrupole resonance studies of the phase transitions of para-dichlorobenzene

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