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Issue 4, 1979
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Interactions of tetrakis-µ-acetato-dirhodium(II) with adenine nucleosides and nucleotides

Abstract

Reactions of the antitumour complex [Rh2(O2CMe)4] with adenine nucleosides and nucleotides have been studied in aqueous solutions. Both 1 : 1 and 1 : 2 solid adducts have been isolated and characterized by elemental analyses and i.r., visible, and 1H n.m.r. spectra. The results indicate that the 1 : 1 adenine derivatives form polymeric bridged adducts with both N(1) and N(7) sites bonded to RhII. The only exception is tetra-acetyladenosine which forms 1 : 2 adducts in which only the N(7) site is involved in bonding to RhII.

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Article type: Paper
DOI: 10.1039/DT9790000596
Citation: J. Chem. Soc., Dalton Trans., 1979,0, 596-599
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    Interactions of tetrakis-µ-acetato-dirhodium(II) with adenine nucleosides and nucleotides

    G. Pneumatikakis and N. Hadjiliadis, J. Chem. Soc., Dalton Trans., 1979, 0, 596
    DOI: 10.1039/DT9790000596

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