Identification of binuclear acyl complexes as intermediates in the CO-induced conversion of [(η5-C5H5)Co(CO)(Me)]2 into acetone, and [(η5-C5H5)Co(CO)(Et)]2 into pentan-3-one

Mary Ann White; Robert G. Bergman

doi:10.1039/C39790001056

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Journal of the Chemical Society, Chemical Communications

Issue 23, 1979

Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.

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Identification of binuclear acyl complexes as intermediates in the CO-induced conversion of [(η⁵-C₅H₅)Co(CO)(Me)]₂ into acetone, and [(η⁵-C₅H₅)Co(CO)(Et)]₂ into pentan-3-one

Mary Ann White and Robert G. Bergman

J. Chem. Soc., Chem. Commun., 1979, 1056-1058

DOI: 10.1039/C39790001056

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Abstract
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Studies of the carbonylation of [(η⁵-C₅H₅)Co(CO)(R)]₂(R = Me, Et) at temperatures below ambient have revealed that these complexes may be converted into ketones via binuclear diacyl complexes [(η⁵-C₅H₅)Co(CO)(COR)]₂; the postulated mechanistic pathway circumvents the earlier-identified intermediate (η⁵-C₅H₅)Co(CO)R₂, and involves alkyl transfer from a Co^II acyl complex as a critical step.

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Journal of the Chemical Society, Chemical Communications

Identification of binuclear acyl complexes as intermediates in the CO-induced conversion of [(η⁵-C₅H₅)Co(CO)(Me)]₂ into acetone, and [(η⁵-C₅H₅)Co(CO)(Et)]₂ into pentan-3-one

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Journal of the Chemical Society, Chemical Communications

Identification of binuclear acyl complexes as intermediates in the CO-induced conversion of [(η5-C5H5)Co(CO)(Me)]2 into acetone, and [(η5-C5H5)Co(CO)(Et)]2 into pentan-3-one

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Identification of binuclear acyl complexes as intermediates in the CO-induced conversion of [(η⁵-C₅H₅)Co(CO)(Me)]₂ into acetone, and [(η⁵-C₅H₅)Co(CO)(Et)]₂ into pentan-3-one