Issue 11, 1979

Trimethylphosphine complexes of rhodium(I) and ruthenium(II); X-ray crystal structures of chlorotristrimethylphosphinerhodium and tetrakistrimethylphosphinerhodium chloride

Abstract

The syntheses are reported of the rhodium(I) and ruthenium(II) trimethylphosphine complexes RhCl(PMe3)3, [Rh(PMe3)4]Cl, η5-C5H5Rh(PMe3)2, CHg6Rh4(PMe3)12, trans-RuCl2(PMe3)4, [Ru2Cl2(PMe3)8]Cl2, and [RuCl(PMe3)4]BF4 and of ruthenium(I), Ru2Cl2(PMe3)4; the structures of RhCl(PMe3)3 and [Rh(PMe3)4]Cl have been determined by single crystal X-ray analysis.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 489-490

Trimethylphosphine complexes of rhodium(I) and ruthenium(II); X-ray crystal structures of chlorotristrimethylphosphinerhodium and tetrakistrimethylphosphinerhodium chloride

R. A. Jones, F. M. Real, G. Wilkinson, A. M. R. Galas, M. B. Hursthouse and K. M. A. Malik, J. Chem. Soc., Chem. Commun., 1979, 489 DOI: 10.1039/C39790000489

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