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Issue 12, 1978
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Cycloadditions to conjugated diallenes


Conjugated diallenes of the general structure (1) reacted with N-phenyl-1,2,4-triazoline-3,5-dione (5) to give [4 + 2] cycloaddition products; the meso-diallene (4) with (5) gave the unsymmetrical Diels–Alder adduct (8) and the ‘ene’ product (9). Reaction of diallene (2) with sulphinylaniline gave the Diels–Alder product (11) while reactions with ketens resulted in both [2 + 2] and [4 + 2] cycloaddition products.

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Article type: Paper
DOI: 10.1039/P19780001568
Citation: J. Chem. Soc., Perkin Trans. 1, 1978, 1568-1572
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    Cycloadditions to conjugated diallenes

    C. Boan and L. Skattebøl, J. Chem. Soc., Perkin Trans. 1, 1978, 1568
    DOI: 10.1039/P19780001568

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