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Issue 7, 1978
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Stereospecific synthesis from non-carbohydrate precursors of the deoxy- and methyl-branched deoxy-sugars L-amicetose, L-mycarose, and L-olivomycose

Claudio Fuganti  and  Piero Grasselli 

Abstract

2,3,6-Trideoxy-L-erythro-hexose (L-amicetose)(12), 2,6-dideoxy-3-C-methyl-L-ribo-hexose (L-mycarose)(13), and 2,6-dideoxy-3-C-methyl-L-arabino-hexose (L-olivomycose)(14) have been synthesized from the corresponding lactones (9), (10), and (11), obtained, in turn, upon cleavage with ozone of the aromatic ring of suitable derivatives of the aromatic, C6–C5 optically active methyl diols (1) and (2) prepared from the C6–C3αβ-unsaturated aldehydes and fermenting baker's yeast.

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Article type: Paper
DOI: 10.1039/C39780000299
Citation: J. Chem. Soc., Chem. Commun., 1978,0, 299-300
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    Stereospecific synthesis from non-carbohydrate precursors of the deoxy- and methyl-branched deoxy-sugars L-amicetose, L-mycarose, and L-olivomycose

    C. Fuganti and P. Grasselli, J. Chem. Soc., Chem. Commun., 1978, 0, 299
    DOI: 10.1039/C39780000299

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