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Issue 6, 1978
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An unusually stable thionitrite from N-acetyl-D,L-penicillamine; X-ray crystal and molecular structure of 2-(acetylamino)-2-carboxy-1,1-dimethylethyl thionitrite

Abstract

N-Acetyl-D,L-penicillamine (1) was converted by HNO2 into a thionitrite (3) which was stable as a solid and atypically so even in solution; X-ray structural parameters are given for (3), and both homolytic and heterolytic reactions are described.

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Article type: Paper
DOI: 10.1039/C39780000249
Citation: J. Chem. Soc., Chem. Commun., 1978, 249-250
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    An unusually stable thionitrite from N-acetyl-D,L-penicillamine; X-ray crystal and molecular structure of 2-(acetylamino)-2-carboxy-1,1-dimethylethyl thionitrite

    L. Field, R. V. Dilts, R. Ravichandran, P. G. Lenhert and G. E. Carnahan, J. Chem. Soc., Chem. Commun., 1978, 249
    DOI: 10.1039/C39780000249

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