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Issue 6, 1978
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Reactions of nitrogen oxides with di(cyclopentadienyl)titanium complexes

Frank Bottomley  and  Hans H. Brintzinger 

Abstract

Under various conditions the following reactions between dinitrogen oxide (N2O) or nitrogen mono-oxide (NO) and di(cyclopentadienyl)titanium (Cp2Ti) complexes are found: (i)(Cp2TiCl)2+ 2NO →(Cp2TiCl)2O + N2O; (ii) 2Cp2Ti(CO)2+ 1NO → 3CO + Ti-product; (iii) 2Cp2-Ti(CO)2+ 2NO → 2CO + CO2+ N2+ Ti-product; (iv) Cp2Ti(CO)2+ N2O → N2+ 2CO +(CpTiO)x; (v) Cp2Ti-(CO)2+ 2N2O →(CpTiO)x+ CO + CO2+ 2N2; (vi) CpTi + N2O →(Cp2Ti)2O + N2.

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Article type: Paper
DOI: 10.1039/C39780000234
Citation: J. Chem. Soc., Chem. Commun., 1978,0, 234-235
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    Reactions of nitrogen oxides with di(cyclopentadienyl)titanium complexes

    F. Bottomley and H. H. Brintzinger, J. Chem. Soc., Chem. Commun., 1978, 0, 234
    DOI: 10.1039/C39780000234

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