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Issue 22, 1978
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Insertion of the carbene : CH2 into Ni–R bonds of mono- and di-alkylnickel(II) complexes

Takakazu Yamamoto 

Abstract

The reaction of alkylnickel(II) complexes [NiR2(bpy)] and [NiR(X)L2][R = Me, Et; X = imido, OCOMe; L = bpy (2,2′-bipyridine), 1,2-bis(diphenylphosphino)ethane], with CH2X2(X = Cl, I) afforded RCH2CH2R, RCH2R, RMe, and R(–H)= CH2 in addition to the usual degradation products R–R, RH, and R(–H); these unusual products are considered to be formed through insertion of the carbene: CH2 into the Mi–R bond.

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Article type: Paper
DOI: 10.1039/C39780001003
Citation: J. Chem. Soc., Chem. Commun., 1978,0, 1003-1004
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    Insertion of the carbene : CH2 into Ni–R bonds of mono- and di-alkylnickel(II) complexes

    T. Yamamoto, J. Chem. Soc., Chem. Commun., 1978, 0, 1003
    DOI: 10.1039/C39780001003

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