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Issue 12, 1977
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Kinetics of the reactions of piperidine, n-butylamine, morpholine, and benzylamine with 2,4-dinitrophenyl phenyl ether

Dapo Ayediran,  Titus O. Bamkole,  J. Hirst  and  Ikenna Onyido 

Abstract

The kinetics of the reactions designated in the title have been studied as a function of amine concentration in acetonitrile, dimethyl sulphoxide, and (for piperidine and n-butylamine only) methanol. In all the solvents studied, the reactions of the secondary amines are base-catalysed : those of the primary amines are not. The results are interpreted in terms of the generally accepted mechanism of nucleophilic aromatic substitution.

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Article type: Paper
DOI: 10.1039/P29770001580
Citation: J. Chem. Soc., Perkin Trans. 2, 1977,0, 1580-1583
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    Kinetics of the reactions of piperidine, n-butylamine, morpholine, and benzylamine with 2,4-dinitrophenyl phenyl ether

    D. Ayediran, T. O. Bamkole, J. Hirst and I. Onyido, J. Chem. Soc., Perkin Trans. 2, 1977, 0, 1580
    DOI: 10.1039/P29770001580

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