Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron

J. Richard Blackborow; Robert H. Grubbs; Knut Hildenbrand; E. A. Koerner von Gustorf; Akira Miyashita; Alberto Scrivanti

doi:10.1039/DT9770002205

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Journal of the Chemical Society, Dalton Transactions

Issue 22, 1977

The international journal for inorganic, organometallic and bioinorganic chemistry

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Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron

J. Richard Blackborow, Robert H. Grubbs, Knut Hildenbrand, E. A. Koerner von Gustorf, Akira Miyashita and Alberto Scrivanti

J. Chem. Soc., Dalton Trans., 1977, 2205-2209

DOI: 10.1039/DT9770002205

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Abstract
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Evidence for a 1,2-shift mechanism of the 1–5-η-cycloheptatrienyl moiety with respect to the central iron atom of the title compound is presented together with absolute assignments of the ¹³C n.m.r. chemical shifts of the C₇H₇ ring. A low-temperature rocking motion of both rings can be frozen out at –70 °C.

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J. Richard Blackborow
Robert H. Grubbs
Knut Hildenbrand
E. A. Koerner von Gustorf
Akira Miyashita
Alberto Scrivanti

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Journal of the Chemical Society, Dalton Transactions

Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron

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Journal of the Chemical Society, Dalton Transactions

Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron

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