Ab initio-LCAO–MO–SCF calculations indicate that the hydrogen-bond between the fluoride anion and formic acid, HCO2H ⋯ F–, is stronger than that in the bifluoride anion, F–H ⋯ F–, previously believed to be the upper limit of H-bond strength.
J. Emsley, O. P. A. Hoyte and R. E. Overill, J. Chem. Soc., Chem. Commun., 1977, 225 DOI: 10.1039/C39770000225
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