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Issue 9, 1976
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Preparation and properties of difluoro(difluorophosphinoamino)borane

Abstract

Aminodifluorophosphine and boron trifluoride react in the gas or liquid phase to give an adduct, which decomposes into difluoro(difluorophosphinoamino)borane, BF2[NH(PF2)], which has been characterised by mass, photoelectron, n.m.r., and vibrational spectoscopy. With excess of PF2(NH2), the adduct reacts further to give bis(difluorophosphino)amine, NH(PF2)2, and the ammonia–trifluoroborane adduct.

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Article type: Paper
DOI: 10.1039/DT9760000823
Citation: J. Chem. Soc., Dalton Trans., 1976, 823-825
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    Preparation and properties of difluoro(difluorophosphinoamino)borane

    D. E. J. Arnold, E. A. V. Ebsworth and D. W. H. Rankin, J. Chem. Soc., Dalton Trans., 1976, 823
    DOI: 10.1039/DT9760000823

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