Jump to main content
Jump to site search

Issue 21, 1976
Previous Article Next Article

1,5-Shift of unsaturated groups


Racemisation rates for the indenes (1) provide migratory aptitudes for acyl, vinyl, ethynyl, nitrile, and alkyl groups, as well as hydrogen; it is proposed that the fast migration of formyl, acetyl, and benzoyl groups is, at least in part, due to a secondary interaction involving the carbonyl π* orbital.

Back to tab navigation

Article type: Paper
DOI: 10.1039/C39760000873
Citation: J. Chem. Soc., Chem. Commun., 1976,0, 873-874
  •   Request permissions

    1,5-Shift of unsaturated groups

    D. J. Field, D. W. Jones and G. Kneen, J. Chem. Soc., Chem. Commun., 1976, 0, 873
    DOI: 10.1039/C39760000873

Search articles by author