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Issue 21, 1976
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1,5-Shift of unsaturated groups

Abstract

Racemisation rates for the indenes (1) provide migratory aptitudes for acyl, vinyl, ethynyl, nitrile, and alkyl groups, as well as hydrogen; it is proposed that the fast migration of formyl, acetyl, and benzoyl groups is, at least in part, due to a secondary interaction involving the carbonyl π* orbital.

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Article type: Paper
DOI: 10.1039/C39760000873
Citation: J. Chem. Soc., Chem. Commun., 1976,0, 873-874
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    1,5-Shift of unsaturated groups

    D. J. Field, D. W. Jones and G. Kneen, J. Chem. Soc., Chem. Commun., 1976, 0, 873
    DOI: 10.1039/C39760000873

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