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Issue 19, 1976
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Mechanism of action of the vitamin B12-dependent enzyme dioldehydrase: refinement of a model system involving photodecomposition of dihydroxyalkylcobaloximes

Bernard T. Golding,  Charles S. Sell  and  Philip J. Sellars 

Abstract

Anaerobic photolysis of the following cobaloximes in 0.1 M acetic acid gives the carbonyl-containing products(s) in parentheses: 3,4-dihydroxybutyl(pyridine)-cobaloxime (none), 4,5-dihydroxypentyl(aquo)cobaloxime (10% pentanal), 5,6-dihydroxyhexyl(pyridine)cocobaloxime (16% hexan-2-one +ca. 4% hexanal); these findings strengthen a model system proposed for the vitamin 12-dependent enzyme dioldehydrase.

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Article type: Paper
DOI: 10.1039/C39760000773
Citation: J. Chem. Soc., Chem. Commun., 1976,0, 773-774
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    Mechanism of action of the vitamin B12-dependent enzyme dioldehydrase: refinement of a model system involving photodecomposition of dihydroxyalkylcobaloximes

    B. T. Golding, C. S. Sell and P. J. Sellars, J. Chem. Soc., Chem. Commun., 1976, 0, 773
    DOI: 10.1039/C39760000773

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