Issue 21, 1976
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation of two isomers of [Ru(S2CH)(PMe2Ph)4]PF6 and the characterisation of the purple one as a five-co-ordinate ruthenium(II) salt containing a phosphonium adducts of a dithioformato ligand. The X-ray crystal structure of [Ru{S2C(H)PMe2Ph}(PMe2Ph)3]PF6

Terence V. Ashworth,   Eric Singleton  and  Michael Laing  

Abstract

The purple salt [Ru{S2C(H)PMe2Ph}(PMe2Ph)3]-PF6, shown by X-ray analysis to contain a phosphoniumbetaine group, and formed by a sterically-controlled rearrangement of the orange dithioformato complex [Ru(S2CH)(PMe2Ph)4]PF6, undergoes a reverse rearrangement during substitution reactions with P(OMe)3.

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Article information

DOI
https://doi.org/10.1039/C39760000875
Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 875-876

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Preparation of two isomers of [Ru(S2CH)(PMe2Ph)4]PF6 and the characterisation of the purple one as a five-co-ordinate ruthenium(II) salt containing a phosphonium adducts of a dithioformato ligand. The X-ray crystal structure of [Ru{S2C(H)PMe2Ph}(PMe2Ph)3]PF6

T. V. Ashworth, E. Singleton and M. Laing, J. Chem. Soc., Chem. Commun., 1976, 875 DOI: 10.1039/C39760000875

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