An intermediate in the thermal decomposition of N-amino-7-azabicyclo[2.2.1]heptane and the corresponding benzenesulphonamide derivative, whose structure is consistent with the formulation 7-azabicyclo[2.2.1]heptane N-imide, affords on thermal fragmentation the hydrocarbon products hexa-1,5-diene, bicyclo[2.2.0]hexane, and cyclohexene and does not rearrange to the corresponding stable 2,3-diazabicyclo[2.2.2]oct-2-ene isomer.
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Journal of the Chemical Society, Chemical Communications
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