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Issue 15, 1975
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Studies on the reactions between nitric oxide and conjugated dienes

Peter B. Brindley  and  Simon H. Nicholson 

Abstract

Chlorine-substituted dienes interact with nitric oxide to form low molecular weight polymers. Initiation is by addition of nitric oxide. The short chain polymerisation is terminated by a cage reaction with nitrogen trioxide or by addition of nitric oxide, the nitroso-end group reacting further to form oximes and nitriles. Less reactive dienes gave similar products, there being a tendency for the chain reaction to give monomeric nitromono-olefins and mono-olefinic nitrates.

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Article type: Paper
DOI: 10.1039/P29750001808
Citation: J. Chem. Soc., Perkin Trans. 2, 1975,0, 1808-1813
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    Studies on the reactions between nitric oxide and conjugated dienes

    P. B. Brindley and S. H. Nicholson, J. Chem. Soc., Perkin Trans. 2, 1975, 0, 1808
    DOI: 10.1039/P29750001808

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