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Issue 20, 1975
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Synthesis and X-ray structure of bis(diethyldithiocarbamato)(µ-dichloro)-dicopper(II), Cu2(Et2dtc)2Cl2, and the X-ray structure of Cu3(Et2dtc)2Cl3, an unusual mixed valence CuII, CuI reduction product

Abstract

The preparation and crystal structure of the dimeric chloro-bridged copper(II) dithiocarbamate complex, Cu2(Et2dtc)2Cl2, are described, together with the crystal structure of a related minor product, Cu3(Et2dtc)2-Cl3, which proves to be an unusual mixed valence CUII/CUI polymer.

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Article type: Paper
DOI: 10.1039/C39750000843
Citation: J. Chem. Soc., Chem. Commun., 1975,0, 843-844
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    Synthesis and X-ray structure of bis(diethyldithiocarbamato)(µ-dichloro)-dicopper(II), Cu2(Et2dtc)2Cl2, and the X-ray structure of Cu3(Et2dtc)2Cl3, an unusual mixed valence CuII, CuI reduction product

    A. R. Hendrickson, R. L. Martin and D. Taylor, J. Chem. Soc., Chem. Commun., 1975, 0, 843
    DOI: 10.1039/C39750000843

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