Issue 20, 1975

Retention of stereochemistry at both platinum centres in the symmetrisation reaction between cis-[PtMe2(PMe2Ph)2] and cis-[Pt(NO3)2(PMe2Ph)2]

Abstract

Reaction of cis-[PtMe2(PMe2Ph)2] with cis-[Pt(NO3)2(PMe2Ph)2] in dichloromethane solution gives only cis-[PtMe(NO3)(PMe2Ph)2] which then isomerises slowly to the more stable trans-isomer.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 841-842

Retention of stereochemistry at both platinum centres in the symmetrisation reaction between cis-[PtMe2(PMe2Ph)2] and cis-[Pt(NO3)2(PMe2Ph)2]

P. J. Thompson and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1975, 841 DOI: 10.1039/C39750000841

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