Photoelectron spectroscopy is used to show that benzylmercuric chloride exists in the vapour phase in a conformation where the carbon–mercury bond can interact with the π system of the aromatic ring.
H. Schmidt, A. Schweig and G. Manuel, J. Chem. Soc., Chem. Commun., 1975, 667 DOI: 10.1039/C39750000667
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